The module is available to all students on the above programmes and is offered to suitably qualified occasional students. For the latter, enrolment is determined on a case-by-case basis using academic transcripts.
Contact Hours
Lecture-28 hours
Practical Classes and workshops-3 hours Total: 31 hours
Exclusions
Description
This module applies the principles and concepts delivered in Levels 1 and 2 (in a range of modules) to a number of topical areas in inorganic materials chemistry, drawn from across the entire periodic table. The topics covered in this module include: band theory, properties and uses of semiconductors, zeolites and other silicates and an overview of chemistry of the f-block metals.
Learning Outcomes
By the end of the module students should be able to:
Demonstrate an understanding of the (advanced) principles and concepts associated with the material delivered in each area;
Apply their acquired knowledge to the solution of relevant problems;
Appreciate the breadth of inorganic chemistry, through exposure to a number of topical subject areas;
Appreciate and discuss some important applications of inorganic chemistry (as a discipline) within the context of the course.
Understand the principles of band formation in solids;
Describe and explain the difference between the band structures of metals, semiconductors and insulators;
Understand what is meant by the terms Fermi energy and density of states;
Understand the terms intrinsic, extrinsic, donor, acceptor, n-type and p-type in relation to semiconductors;
Describe basic applications of semiconductors, e.g. thermistors, photoconductors, p–n junctions, LEDs;
Correlate electronic structure properties with reactivity of lanthanides and actinides;
Compare properties of lanthanide and actinide elements with transition metals;
Deduce ground term symbols of lanthanides and discuss spectroscopic properties of compounds of these elements;
Explain the more common coordination numbers and geometries in lanthanide complexes;
Explain trends and patterns in lanthanide chemistry, relating them to the lanthanide contraction when appropriate;
Recall features of key organometallic compounds of these elements, and know of the significant differences between the organometallic chemistry of the d- and f- block elements;
Design ligands for several applications of lanthanides ranging from solid state phosphors to biological imaging;
Appreciate the importance of silicates in geochemistry and industrial applications;
Describe and explain the basic crystal chemical principles that can be used to describe the structures of all solid silicates;
Describe and explain the structures of layered silicates, such as clays, and correlate the structures with physical and chemical properties;
Discuss the variability in the chemical compositions of zeolites, knowing how to control it and how it affects the physical and chemical properties;
Describe how the framework topologies and porosities of zeolites are derived and the interrelationship between these and their chemical applications;
Understand why zeolites are used so widely in industry.
Formal Written Unseen Examination - 100 % An end of session examination contributes 100 % to the overall module mark. The examination is 2 hours in duration and is closed book. The exam assessment for this module is linked to the module title: Inorganic Chemistry I (03 10851) Reassessment: No opportunity for reassessment