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Module Title Quantum Mechanics and Atomic Spectroscopy
SchoolChemistry
Department Chemistry
Module Code 03 21452
Module Lead Dr Horswell
Level Intermediate Level
Credits 10
Semester Semester 1
Pre-requisites
Co-requisites Non-ideal Thermodynamics and Equilibrium Electrochemistry - (03 21450)
Restrictions None
Contact Hours Lecture-18 hours
Tutorial-2 hours
Practical Classes and workshops-12 hours
Total: 32 hours
Exclusions
Description

This module is composed of two inter-related components. The module starts with Quantum Mechanics, which is fundamental to our understanding of matter and the way in which atoms and molecules interact with light; i.e., spectroscopy. The course introduces quantum mechanics, starting from its development to explain failures of classical mechanics, through to its application to atoms and its use to understand the spectra of one- and many-electron atoms/ions. It is also shown how electronic configurations give rise (through electrostatic interactions) to terms, which are split by the magnetic coupling of spin and orbital angular momenta into (J) levels, which may be further split into states in a magnetic field. Next, the electronic spectra of atoms is discussed, including the electronic spectra of many electron atoms. The laboratory component further develops some theoretical aspects of the module, and provides further experience in conducting physical chemistry experiments.

Learning Outcomes By the end of the module the student should be able to:
  • Demonstrate a basic knowledge of the principles of Quantum Mechanics, within the context of the course;
  • Apply their knowledge of Quantum Mechanics to the solution of problems;
  • Demonstrate an understanding of the principles and concepts underlying Electronic Spectroscopy, including selection rules;
  • Assign ground terms, and assign microstates to terms;
  • Predict and rationalise the electronic spectra for many electron atoms and ions;
  • Demonstrate the ability to perform experiments in Physical Chemistry, collect and interpret data and present the results obtained in a coherent manner.
Assessment 21452-01 : Exam : Exam (Centrally Timetabled) - Written Unseen (75%)
21452-02 : Practical : Practical (25%)
Assessment Methods & Exceptions Assessments: Laboratory-based work: total of 25% - Laboratory-based work contributes a total of 25% to the overall module mark. The laboratory mark consists of a number of components, namely maintaining a diary, accreditation of skills and laboratory reports Formal Written Unseen Examination: 75% - An end of session examination contributes 75% to the overall module mark; the exam is 2 hours in duration and is closed book. The exam assessment for this module is linked to the module titled Non-ideal Thermodynamics and Equilibrium Electrochemistry (03 21452). Reassessment: If a student fails to pass the module at the first attempt, the end of session examination may be taken as a resit with the mark capped at 40%.
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